Compliance Scenarios for Four Types of Plastic Packaging Materials: PET/PVC/PP/PE—Printers Most Commonly Run into Trouble with Phthalates in PVC
💡 💡 At a Glance
A customer manufactures PVC packaging bags for children's toys for export. After being selected for inspection by German customs, the bags were found to exceed the DEHP limit by 8 times, resulting in the destruction of the entire batch of 20000 bags. This article details the compliance boundaries of 4 types of plastic packaging materials—PET, PVC, PP, and PE—in 4 application scenarios: food, cosmetics, pharmaceuticals, and toys. Printers are most likely to run into trouble with the phthalate limits for PVC (DEHP/DBP)—the EU limit is 0.1%, and mandatory requirements are now also beginning to apply domestically to food packaging.
In September 2024, a customer exporting children's toys received a return shipment. The customer's original statement:
“We make PVC packaging bags for children’s toys. When our shipment was randomly inspected by German customs, the DEHP content exceeded the limit by 8 times—the German limit is 0.1%, while the tested value for this batch was 0.8%. All 20000 bags in the batch were destroyed, resulting in a loss of 80000 yuan.”
This is a genuine regulatory minefield. Before accepting orders for plastic packaging, printing plants must clarify the compliance boundaries for 4 types of materials across 4 types of applications.
Type I material: PET (polyethylene terephthalate)
Properties: Transparent, good stiffness, and temperature resistant from -40°C to 70°C. Common uses: beverage bottles, cosmetic bottles, and food container covers.
Compliance scenarios:
Attention printing plants: PET has high transparency and therefore places strict demands on inks. Ordinary UV inks tend to delaminate on PET, so PET-specific UV inks or water-based inks are recommended. Our printing plant has encountered 3 cases of UV ink delamination on PET. After switching to PET-specific UV ink, the pass rate reached 100%.
PET also has an easily overlooked characteristic: crystallinity. PET with a crystallinity above 30% is highly transparent, whereas PET with a crystallinity below 30% tends to be milky white. When printers purchase raw materials, they should confirm the transparency grade required by the customer.
Type 2 Material: PVC (Polyvinyl Chloride)
Properties: Transparent, flexible, and heat-sealable. Common uses: Toy packaging, food cling film, cosmetic tubes, and bank cards.
Compliance scenarios (where printing plants are most likely to run into trouble):
Printer Iron Rule: Before accepting a PVC order, you must ask the customer 4 questions:
Our printing plant declined 2 PVC orders in 2024: one was for children's toys destined for export, and the raw material supplier's product grades contained DEHP; the other was for food packaging destined for the European Union. If we had accepted these two orders, the losses would have exceeded 500,000.
Type 3 Material: PP (Polypropylene)
Properties: Temperature resistance from -20°C to 120°C, translucent, and good rigidity. Common applications: food containers, cosmetic bottle caps, pharmaceutical packaging, and drinking straws.
Compliance scenarios:
Printer’s attention: PP has low surface energy, and ink adhesion is poorer than on PET. We recommend corona treatment before printing (corona strength ≥38 dynes). Our printing plant uses inline corona treatment, with a corona strength of 38-42 dynes, reducing the PP printing delamination rate from 8% to below 1%.
PP is also divided into homopolymer PP and copolymer PP. Homopolymer PP has poor transparency but good stiffness, making it suitable for bottle caps; copolymer PP has good transparency but poor stiffness, making it suitable for film. When a printing plant purchases raw materials, it should clarify with the customer which type of PP is required.
Type 4 Material: PE (Polyethylene)
Properties: Soft, moisture-resistant, and easy to heat-seal. Common applications: Food bags, cling film, personal care product bottles, and pipes.
Compliance scenarios:
PE is divided into LDPE (low density, soft), HDPE (high density, good stiffness), and MDPE (medium density). The printing plant must clarify which type of PE the customer requires when accepting an order.
PE is most likely to cause problems in this scenario: A customer purchases PE bags for food packaging, only to find that the bag’s inner layer is made from recycled PE, which is not permitted for food contact in either the European Union or China. Our printing plant requires proof of food-grade raw materials (FDA or EFSA certification) for all PE food packaging orders.
4 Iron Rules for Printing Factories Taking on Plastic Packaging Orders
3 Common Misconceptions About Plastic Packaging Compliance
Further Reading
FAQ
Can PVC packaging be used for food contact?
Permitted in China (GB 4806.7), but vinyl chloride monomer migration must be <1 mg/kg. The EU has banned PVC from food contact since 2020. Printers must clarify the destination before taking export orders.
Which is more suitable for food packaging, PET or PP?
Depends on the scenario. PET has high transparency and suits beverage bottles and cosmetic outer covers; PP has high temperature resistance and suits microwave food boxes and bottle caps. Both materials are compliant.
What are the hazards of exceeding phthalate (DEHP) limits?
DEHP is an endocrine disruptor, and long-term exposure affects the reproductive system. The EU limit is 0.1%, and exceeding it leads to destruction. Printers making children's toy packaging must use PVC without DEHP or switch to PET/PE.
Is PE really eco-friendly?
PE is recyclable (recycling codes 02/04), but not biodegradable. Laboratory data shows PE takes 100-500 years to decompose in the natural environment. Be rigorous with eco-friendly claims—do not say PE is biodegradable.
How to handle ink delamination on plastic packaging?
Plastic surface energy is low (PP/PE surface energy 30-32 mN/m), so corona treatment (≥38 dyne) is needed before printing. If delamination has already occurred, reprint with PP/PE-specific ink, or switch to PET-specific UV ink.
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